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Priv.-Doz. Dr. Heinrich Lang Novel Carbon Compounds with “Naked” Cn Units Angewandte Chemie International Edition in English 33

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199405471

1,3-Dimetallaallenes 1 or carbyne complexes 2 are the simplest examples of compounds in which different transition metal complex fragments or units of main group elements are terminally bound to Cn bridges. Polymers such as 3 with C4 bridges which link d8 ML2 building blocks are of particular interest as materials with novel properties.

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