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Dr. Stephen A. Hitchcock, Serge H. Boyer, Margaret Y. Chu-Moyer, Steven H. Olson and Prof. Samuel J. Danishefsky A Convergent Total Synthesis of Calicheamicin γ 1I Angewandte Chemie International Edition in English 33

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199408581

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Ultimate convergence for the total synthesis of calicheamicin γmath image has been achieved thanks to a remarkable glycosidation between the glycosyl donor 2 and aglycone ent-1 (see preceeding communication; R = SSMe, ketal-protected); after glycosidation the natural product is obtained in two steps.

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