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Dr. Karl-Josef Haack, Dr. Shohei Hashiguchi, Dr. Akio Fujii, Dr. Takao Ikariya and Prof. Dr. Ryoji Noyori The Catalyst Precursor, Catalyst, and Intermediate in the RuII-Promoted Asymmetric Hydrogen Transfer between Alcohols and Ketones Angewandte Chemie International Edition in English 36

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199702851

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New insight into the mechanism of catalysis. The purple 16-electron complex 1 and the yellow 18-electron complex 2 directly mediate the asymmetric, RuII-catalyzed hydrogen transfer between secondary alcohols and ketones. Both complexes were characterized by X-ray crystallography.

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