Sabine Kainz, Daniel Koch, Priv.-Doz. Dr. Walter Leitner and Dr. Wolfgang Baumann Perfluoroalkyl-Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide Angewandte Chemie International Edition in English 36
The solubility of complexes is one decisive factor for their use as homogeneous catalysis in supercritical carbon dioxide (scCO2). Complexes with perfluoroalkyl-substituted arylphosphane ligands (shown schematically on the right), which can be prepared by a straightforward and variable synthetic methodology, exhibit high solubility in scCO2 in contrast to unsubstituted parent compounds.
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