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Sabine Kainz, Daniel Koch, Priv.-Doz. Dr. Walter Leitner and Dr. Wolfgang Baumann Perfluoroalkyl-Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide Angewandte Chemie International Edition in English 36

Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199716281

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The solubility of complexes is one decisive factor for their use as homogeneous catalysis in supercritical carbon dioxide (scCO2). Complexes with perfluoroalkyl-substituted arylphosphane ligands (shown schematically on the right), which can be prepared by a straightforward and variable synthetic methodology, exhibit high solubility in scCO2 in contrast to unsubstituted parent compounds.

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