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Benjamin Greedy, Jean-Marc Paris, Thierry Vidal and Véronique Gouverneur Regio- and Enantioselective Synthesis of Allylic Fluorides by Electrophilic Fluorodesilylation of Allyl Silanes Angewandte Chemie International Edition 42

Version of Record online: 16 JUL 2003 | DOI: 10.1002/anie.200351405

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EnantiopureN-fluorocinchona alkaloids promoted the electrophilic fluorodesilylation of allyl silanes in a conceptually new approach to the regio- and enantioselective formation of allylic fluorides (see scheme). Excellent conversions were observed in these reactions, which afforded the desired allylic fluorides with up to 96 % ee.

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