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Craig J. Matthews, Stuart T. Onions, Gérald Morata, Lisa J. Davis, Sarah L. Heath and Daniel J. Price A Self-Assembled Tetracopper Triple-Stranded Helicate: Towards the Controlled Synthesis of Finite One-Dimensional Magnetic Chains Angewandte Chemie International Edition 42

Version of Record online: 23 JUN 2003 | DOI: 10.1002/anie.200351634

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Spiraling into control: A finite linear arrangement of four magnetically coupled copper(II) centers has been generated within a triple-stranded helical motif that was formed through a strict self-assembly process between a single octadentate ligand and CuII ions (see picture). This approach opens the way to constructing finite one-dimensional magnetic chains in a controlled manner.

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