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Jun Huang, Tao Jiang, Haixiang Gao, Buxing Han, Zhimin Liu, Weize Wu, Yanhong Chang and Guoying Zhao Pd Nanoparticles Immobilized on Molecular Sieves by Ionic Liquids: Heterogeneous Catalysts for Solvent-Free Hydrogenation Angewandte Chemie International Edition 43

Article first published online: 2 MAR 2004 | DOI: 10.1002/anie.200352682

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A three-piece suite: The immobilization of a Pd-nanoparticle catalyst onto the surface of a molecular sieve by an ionic liquid (1,1,3,3-tetramethylguanidinium lactate) has been accomplished (see TEM image). The nanoparticle/ionic liquid/molecular sieve combination exhibits excellent synergistic effects that enhance the activity and durability of the catalyst for the hydrogenation of olefins.

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