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Hiromi Torii, Masakazu Nakadai, Kazuaki Ishihara, Susumu Saito and Hisashi Yamamoto Asymmetric Direct Aldol Reaction Assisted by Water and a Proline-Derived Tetrazole Catalyst Angewandte Chemie International Edition 43

Article first published online: 16 MAR 2004 | DOI: 10.1002/anie.200352724

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Just add water to improve the performance of direct aldol reactions like that shown. Previously, aldehydes with high water-affinity or -solubility were considered unsuitable for asymmetric synthesis.

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