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Alexey A. Goryunkov, Vitaliy Y. Markov, Ilya N. Ioffe, Robert D. Bolskar, Michael D. Diener, Igor V. Kuvychko, Steven H. Strauss and Olga V. Boltalina C74F38: An Exohedral Derivative of a Small-Bandgap Fullerene with D3 Symmetry Angewandte Chemie International Edition 43

Article first published online: 11 FEB 2004 | DOI: 10.1002/anie.200352960

Thumbnail image of graphical abstract

Experimental support for the IPR-D3h structure of the empty-cage C74 fullerene (IPR=isolated pentagon rule) has been obtained from an exohedral derivative of the small-bandgap fullerene D3-C74F38 (see picture). Selective fluorination is proposed as a general procedure for protecting nonextractable fullerenes and their endohedral derivatives.

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