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Christophe Copéret, Mathieu Chabanas, Romain Petroff Saint-Arroman and Jean-Marie Basset Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry Angewandte Chemie International Edition 42

Article first published online: 16 JAN 2003 | DOI: 10.1002/anie.200390072

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All sorts of improvements to heterogeneous catalysts are possible through surface organometallic chemistry. This method allows the structures of complexes grafted onto silica surfaces to be studied (see scheme). From this data, the elementary steps of the catalytic process can be deduced and structure–activity relationships developed, which results in a better understanding of the catalytic process.

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