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Andreas Schnepf and Ralf Köppe [Ge8{N(SiMe3)2}6]: A Ligand-Stabilized Ge Cluster Compound with Formally Zero-Valent Ge Atoms Angewandte Chemie International Edition 42

Version of Record online: 21 FEB 2003 | DOI: 10.1002/anie.200390241

Thumbnail image of graphical abstract

Starting from germanium(I) bromide, which can be obtained by preparative co-condensation, the first polyhedral Ge cluster [Ge8{N(SiMe3)2}6] (see picture) has been synthesized in which the average oxidation state of all the Ge atoms in the cluster core lies between 0 and +1.

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