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Sejal J. Patel and Timothy F. Jamison Catalytic Three-Component Coupling of Alkynes, Imines, and Organoboron Reagents Angewandte Chemie International Edition 42

Article first published online: 26 MAR 2003 | DOI: 10.1002/anie.200390349

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An unusual degree of functional group compatibility for imine addition reactions was observed in the assembly of allylic amines from alkynes, imines, and organoboron reagents (boronic acids or boranes) by using a catalyst derived from [Ni(cod)2] and (c-C5H9)3P—this catalytic three-component process (see scheme) is tolerant of ketones, esters, and hydroxylic solvents.

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