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Hisashi Yamamoto and Kentaro Futatsugi “Designer Acids”: Combined Acid Catalysis for Asymmetric Synthesis Angewandte Chemie International Edition 44

Version of Record online: 16 MAR 2005 | DOI: 10.1002/anie.200460394

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An ideal couple: The intramolecular combination of Brønsted and Lewis acids (e.g. acyloxyborane catalyst shown), or of two Lewis acids, or of two Brønsted acids could become a particularly useful tool for the design of asymmetric catalysts with high reactivity, selectivity, and versatility. The inherent reactivity of the associated components is maintained, and the highly organized structures provide an efficient asymmetric environment.

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