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Nathan C. Gianneschi, So-Hye Cho, SonBinh T. Nguyen and Chad A. Mirkin Reversibly Addressing an Allosteric Catalyst In Situ: Catalytic Molecular Tweezers Angewandte Chemie International Edition 43

Article first published online: 13 OCT 2004 | DOI: 10.1002/anie.200460932

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Abiotic allosteric regulation: The design, synthesis, and application of novel, reversible allosteric catalytic molecular tweezers that contain a structural metal, addressable in situ, and two functional catalytic metals are reported (see picture). Kinetic and selectivity data reflect a significant decrease in cooperativity upon opening of the “arms” of the catalyst caused by reactions occurring at the hinge.

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