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Tehshik P. Yoon and Eric N. Jacobsen Highly Enantioselective Thiourea-Catalyzed Nitro-Mannich Reactions Angewandte Chemie International Edition 44

Version of Record online: 29 DEC 2004 | DOI: 10.1002/anie.200461814

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Approaching “privileged” status? A new and highly effective enantioselective catalyst for the nitro-Mannich reaction was identified by modification of thiourea-based Strecker catalysts (see scheme). Products are obtained in high enantiomeric purity and up to 16:1 diastereoselectivity.

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