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Yann Molard, Dario M. Bassani, Jean-Pierre Desvergne, Peter N. Horton, Michael B. Hursthouse and James H. R. Tucker Photorelease of an Organic Molecule in Solution: Light-Triggered Blockage of a Hydrogen-Bonding Receptor Site Angewandte Chemie International Edition 44

Article first published online: 11 JAN 2005 | DOI: 10.1002/anie.200461946

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Bathed in light, the acyclic receptor 1 that binds a neutral guest molecule through hydrogen bonding (12) undergoes an intramolecular anthracene photodimerization reaction to yield a macrocyclic structure. The dramatic change in the structure of 1 from open to cyclic affects the binding properties of the receptor sites and leads to the exclusion of the guest molecule.

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