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Anna Gutowska, Liyu Li, Yongsoon Shin, Chongmin M. Wang, Xiaohong S. Li, John C. Linehan, R. Scott Smith, Bruce D. Kay, Benjamin Schmid, Wendy Shaw, Maciej Gutowski and Tom Autrey Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane Angewandte Chemie International Edition 44

Article first published online: 4 MAY 2005 | DOI: 10.1002/anie.200462602

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Hydrogen-rich materials infused in nanoscaffolds offer a promising approach to on-board hydrogen storage. A mesoporous scaffold decreases the temperature for hydrogen release from ammonia borane (AB), a conventional hydrogen-storage material, to below 80 °C and leads to an increase in the purity of the hydrogen released. (See schematic representation of a hydrogen-bonded AB network in the cross-section of a single pore.)

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