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Christian Bruneau and Pierre H. Dixneuf Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti-Markovnikov Additions to Terminal Alkynes and Alkene Metathesis Angewandte Chemie International Edition 45

Version of Record online: 7 MAR 2006 | DOI: 10.1002/anie.200501391

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Versatile key intermediate metal vinylidenes and allenylidenes participate in numerous catalytic processes such as alkene metathesis, coupling reactions, and anti-Markovnikov additions to alkynes. The formation of a metal vinylidene intermediate in a catalytic reaction (see scheme) was first reported 20 years ago, and much development in the field has since taken place.

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