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Min Serk Kwon, Namdu Kim, Seong Hyeok Seo, In Soo Park, Ravi Kumar Cheedrala and Jaiwook Park Recyclable Palladium Catalyst for Highly Selective α Alkylation of Ketones with Alcohols Angewandte Chemie International Edition 44

Version of Record online: 5 OCT 2005 | DOI: 10.1002/anie.200502422

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An air-stable, heterogeneous, and recyclable catalyst composed of palladium nanoparticles entrapped in aluminum hydroxide was applied to a highly selective α alkylation. A wide range of aliphatic and aromatic ketones and primary alcohols were coupled to prepare enones in an O2 atmosphere and ketones in an argon atmosphere (see scheme).

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