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Cátia Ornelas, Denise Méry, Jean-Claude Blais, Eric Cloutet, Jaime Ruiz Aranzaes and Didier Astruc Efficient Mono- and Bifunctionalization of Polyolefin Dendrimers by Olefin Metathesis Angewandte Chemie International Edition 44

Version of Record online: 25 OCT 2005 | DOI: 10.1002/anie.200502848

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Star- and dendritic-shaped polyolefins can be cleanly and stereospecifically mono- or bifunctionalized by catalytic cross olefin metathesis. Furthermore, this approach provides a rapid overall synthesis of water-soluble dendrimers (see picture) from simple polymethylbenzenes, such as mesitylene and hexamethylbenzene.

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