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Xikui Liu and Ming Jiang Optical Switching of Self-Assembly: Micellization and Micelle–Hollow-Sphere Transition of Hydrogen-Bonded Polymers Angewandte Chemie International Edition 45

Version of Record online: 28 APR 2006 | DOI: 10.1002/anie.200504364

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Light switch: Noncovalently connected micelles are formed by the photoisomerization of azobenzene groups in copolymer building blocks and the hydrogen-bonding interaction within the polymer pair. The UV-induced micellar structure can be fixed through core cross-linking, which allows the reversible optical switching of a micelle–hollow-sphere transition (see picture).

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