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Arkady Krasovskiy, Alexander Tishkov, Vicente del Amo, Herbert Mayr and Paul Knochel Transition-Metal-Free Homocoupling of Organomagnesium Compounds Angewandte Chemie International Edition 45

Version of Record online: 3 JUL 2006 | DOI: 10.1002/anie.200600772

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Without palladium or copper: A wide range of functionalized Grignard compounds were coupled by using diphenoquinone 1 as an electron acceptor. The oxidative dimerization of alkenylmagnesium reagents proceeds with complete retention of the stereochemistry (see scheme; TBDMS=tert-butyldimethylsilyl).

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