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Mircea Dincă, Won Seok Han, Yun Liu, Anne Dailly, Craig M. Brown and Jeffrey R. Long Observation of Cu2+–H2 Interactions in a Fully Desolvated Sodalite-Type Metal–Organic Framework Angewandte Chemie International Edition 46

Article first published online: 19 JAN 2007 | DOI: 10.1002/anie.200604362

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Metal–H2binding: A new tetrazolate-based metal–organic framework exhibits high H2 uptake at low temperature and moderate pressure. The evacuation of coordinated solvent molecules from Cu2+ ions within the framework provides strong binding sites for H2 molecules (see picture; Cu purple, C gray, N blue, Cl green).

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