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Christian Defieber, Martin A. Ariger, Patricia Moriel and Erick M. Carreira Iridium-Catalyzed Synthesis of Primary Allylic Amines from Allylic Alcohols: Sulfamic Acid as Ammonia Equivalent Angewandte Chemie International Edition 46

Article first published online: 12 MAR 2007 | DOI: 10.1002/anie.200700159

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Two for the price of one: Sulfamic acid serves not only as a nitrogen source but also as an in situ activator of hydroxy groups in the first direct iridium-catalyzed synthesis of primary allylic amines from allylic alcohols (see scheme; cod=cycloocta-1,5-diene). The reaction is catalyzed by a commercially available iridium complex and a phosphoramidite-based bidentate phosphorus–olefin ligand.

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