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Sabina Burazerovic, Julieta Gradinaru, Julien Pierron and Thomas R. Ward Hierarchical Self-Assembly of One-Dimensional Streptavidin Bundles as a Collagen Mimetic for the Biomineralization of Calcite Angewandte Chemie International Edition 46

Version of Record online: 24 MAY 2007 | DOI: 10.1002/anie.200701080

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Bundle up: The introduction of streptavidin (as a linker) between two FeII(terpyridine–bis-biotin) connectors affords a one-dimensional metal–organic protein framework (MOPF). In the presence of calcium ions and CO2 vapors, these MOPF aggregates form protein bundles that template the biomineralization of calcite.

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