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Eugene Khaskin, Peter Y. Zavalij and Andrei N. Vedernikov Oxidatively Induced Methyl Transfer from Boron to Platinum in Dimethyldi(2-pyridyl)boratoplatinum Complexes Angewandte Chemie International Edition 46

Article first published online: 19 JUL 2007 | DOI: 10.1002/anie.200701257

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A hydroxlic solvent promoted reaction: Boron-to-platinum methyl-group transfer occurs in the title complexes in the presence of an oxidant (O2 or MeI) and a protic solvent (water, alcohols; see scheme). With MeI as oxidant the reaction intermediate is shown to be a five-coordinate PtIV species containing a Pt⋅⋅⋅CH agostic interaction.

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