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Yu-hong Lam, Carla Bobbio, Ian R. Cooper and Véronique Gouverneur A Concise Synthesis of Enantioenriched Fluorinated Carbocycles Angewandte Chemie International Edition 46

Version of Record online: 5 JUN 2007 | DOI: 10.1002/anie.200701365

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A “reverse” cycloaddition–fluorination strategy has been validated to access enantioenriched fluorinated compounds featuring up to five stereogenic centers, one of which is fluorinated. This highly convergent process features a mild and high-yielding fluorination, for which the sense and level of stereocontrol have been probed.

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