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Véronique Michelet, Patrick Y. Toullec and Jean-Pierre Genêt Cycloisomerization of 1,n-Enynes: Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights Angewandte Chemie International Edition 47

Article first published online: 1 APR 2008 | DOI: 10.1002/anie.200701589

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Rounding it up: Metal-catalyzed cycloisomerization reactions of 1,n-enynes are highly attractive processes as they contribute to the highly demanded search for atom economy. Besides palladium catalysts, several other metals have been identified as excellent catalysts. The molecular complexity of the synthesized products, such as 14, can be greatly enhanced through metal-catalyzed tandem reactions.

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