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Ralf Tonner and Gernot Frenking C(NHC)2: Divalent Carbon(0) Compounds with N-Heterocyclic Carbene Ligands—Theoretical Evidence for a Class of Molecules with Promising Chemical Properties Angewandte Chemie International Edition 46

Version of Record online: 8 OCT 2007 | DOI: 10.1002/anie.200701632

Thumbnail image of graphical abstract

Future targets: Quantum-chemical calculations predict that the experimentally still unknown carbodicarbenes C(NHC)2 (NHC=N-heterocyclic carbene; see picture for example) are a synthetically accessible class of divalent carbon(0) compounds which are very strong nucleophiles and bases that may be useful ligands for transition-metal complexes.

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