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Sigrid Weigelt, Carsten Busse, Christian Bombis, Martin M. Knudsen, Kurt V. Gothelf, Erik Lægsgaard, Flemming Besenbacher and Trolle R. Linderoth Surface Synthesis of 2D Branched Polymer Nanostructures Angewandte Chemie International Edition 47

Article first published online: 29 APR 2008 | DOI: 10.1002/anie.200705079

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Root and branch: A two-dimensional polyimine network (see picture) is formed by condensation polymerization of trialdehydes and diamines co-adsorbed on an Au(111) surface under ultrahigh-vacuum conditions. The local bonding pattern is characterized by STM, which shows that the connectivity of the network is influenced by the kinetic parameters of the preparation procedure.

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