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Shinya Handa, Keita Nagawa, Yoshihiro Sohtome, Shigeki Matsunaga and Masakatsu Shibasaki A Heterobimetallic Pd/La/Schiff Base Complex for anti-Selective Catalytic Asymmetric Nitroaldol Reactions and Applications to Short Syntheses of β-Adrenoceptor Agonists Angewandte Chemie International Edition 47

Version of Record online: 17 MAR 2008 | DOI: 10.1002/anie.200705617

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Two metals in a pod: The combination of Pd and La with a dinucleating Schiff base was developed for anti selectivity in the catalytic asymmetric nitroaldol reaction (see scheme). Short syntheses of β-adrenoceptor agonists by using the heterobimetallic catalyst are presented.

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