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Alois Fürstner, Manuel Alcarazo, Richard Goddard and Christian W. Lehmann Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene” Angewandte Chemie International Edition 47

Version of Record online: 17 MAR 2008 | DOI: 10.1002/anie.200705798

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Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stable ylid- or enolate gold complexes of ene-1,1-diamines not only emulate this property, but also reveal the exceptional donor capacity of such electron-rich olefin ligands. Moreover, the first metal complex of a tetraaminoallene is reported, which features a prototype “carbodicarbene” ligand bound to a transition-metal template.

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