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Dang Sheng Su, Timo Jacob, Thomas W. Hansen, Di Wang, Robert Schlögl, Bert Freitag and Stephan Kujawa Surface Chemistry of Ag Particles: Identification of Oxide Species by Aberration-Corrected TEM and by DFT Calculations Angewandte Chemie International Edition 47

Article first published online: 2 JUN 2008 | DOI: 10.1002/anie.200800406

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Edges and steps have been identified as the locations of surface (O2) and subsurface oxygen atoms (O1) on silver particles by means of DFT calculations and aberration-corrected transmission electron microscopy. The experimental technique allows surface features, such as terraces, steps, and edges, to be clearly imaged (see picture) by eliminating the Fresnel fringes.

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