Mircea Dincă and Jeffrey R. Long Hydrogen Storage in Microporous Metal–Organic Frameworks with Exposed Metal Sites Angewandte Chemie International Edition 47
Getting a grip on hydrogen: Hydrogen typically adsorbs very weakly in physisorptive systems. In microporous materials, however, coordinatively unsaturated metal centers can contribute to an increase in the enthalpy of H2 adsorption. Strategies to incorporate such metal sites in metal–organic frameworks have led to remarkable results within a short period, thus promising to deliver new materials with improved H2 affinity in the near future.
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