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Zhigang Xue, Nguyen Thuy Ba Linh, Seok Kyun Noh and Won Seok Lyoo Phosphorus-Containing Ligands for Iron(III)-Catalyzed Atom Transfer Radical Polymerization Angewandte Chemie International Edition 47

Version of Record online: 15 JUL 2008 | DOI: 10.1002/anie.200801647

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Living polymers: Iron(III) complexes with phosphorus-containing ligands are efficient catalysts for atom transfer radical polymerization in the absence of any radical initiator or reducing agent. The polymers produced have good molecular weights and narrow polydispersities as determined by gel permeation chromatography (see scheme). The controlled nature of the FeBr3/dppp system was confirmed by a chain-extension experiment. Mn,GPC in [g mol−1].

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