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Ganesan Prabusankar, Andreas Kempter, Christian Gemel, Marie-Katrin Schröter and Roland A. Fischer [Sn17{GaCl(ddp)}4]: A High-Nuclearity Metalloid Tin Cluster Trapped by Electrophilic Gallium Ligands Angewandte Chemie International Edition 47

Version of Record online: 20 AUG 2008 | DOI: 10.1002/anie.200802470

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The reduction of SnCl2 by the low-valent gallium(I) β-diketiminate GaI(ddp) gives the title complex, which is best described as a Zintl-type anionic [Sn17]4− cluster stabilized by an electrophilic shell of gallium ligands. This reaction could represent a new concept for the synthesis of metalloid main-group clusters. ddp=HC(CMeNC6H3-2,6-iPr2)2.

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