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Feng Jiao, Jianli Bao, Adrian H. Hill and Peter G. Bruce Synthesis of Ordered Mesoporous Li–Mn–O Spinel as a Positive Electrode for Rechargeable Lithium Batteries Angewandte Chemie International Edition 47

Version of Record online: 6 NOV 2008 | DOI: 10.1002/anie.200803431

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Sturdy spinel: A mesoporous Li–Mn–O spinel (Li1.12Mn1.88O4) with superior rate capability at ambient temperature is synthesized. Comparable stability to the bulk material at elevated temperatures is also observed, despite a surface area of 90 m2 g−1 for the mesopore, suggesting that the internal mesopore surfaces are more stable than the external surface.

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