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Jason M. Spruell, Bonnie A. Sheriff, Dorota I. Rozkiewicz, William R. Dichtel, Rosemary D. Rohde, David N. Reinhoudt, J. Fraser Stoddart and James R. Heath Heterogeneous Catalysis through Microcontact Printing Angewandte Chemie International Edition 47

Version of Record online: 14 NOV 2008 | DOI: 10.1002/anie.200803480

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Minting a Stamp: The preparation of copper metal-coated elastomeric stamps and their use in catalyzing the Cu-catalyzed azide–alkyne cycloaddition reaction heterogeneously through microcontact printing is described (see scheme). This StampCat process is compared to other conventional surface-functionalization techniques, including traditional microcontact printing and solution–surface-based reactions.

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