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Anjian Lan, Kunhao Li, Haohan Wu, David H. Olson, Thomas J. Emge, Woosoek Ki, Maochun Hong and Jing Li A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High Explosives Angewandte Chemie International Edition 48

Version of Record online: 29 JAN 2009 | DOI: 10.1002/anie.200804853

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Sensors and sensitivity: A highly luminescent microporous metal–organic framework, [Zn2(bpdc)2(bpee)] (bpdc=4,4′-biphenyldicarboxylate; bpee=1,2-bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4-dinitrotoluene and the plastic explosive taggant 2,3-dimethyl-2,3-dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra).

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