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Martina Käß, Anja Friedrich, Markus Drees and Sven Schneider Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia–Borane Angewandte Chemie International Edition 48

Version of Record online: 30 DEC 2008 | DOI: 10.1002/anie.200805108

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G“Ru”vy reactivity: The new ruthenium(II) complex having cooperative PNP enamido ligand A reversibly activates two equivalents H2 under reversible hydrogenation of amido (B) and amino (C) complexes. B exhibits the highest reported activities in the dehydrocoupling of ammonia–borane.

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