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Andrea Bernardos, Elena Aznar, María Dolores Marcos, Ramón Martínez-Máñez, Félix Sancenón, Juan Soto, José Manuel Barat and Pedro Amorós Enzyme-Responsive Controlled Release Using Mesoporous Silica Supports Capped with Lactose Angewandte Chemie International Edition 48

Article first published online: 2 JUL 2009 | DOI: 10.1002/anie.200900880

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The great escape: A biocontrolled gated material has been prepared by grafting a lactose derivative onto the pore outlets of a mesoporous support. The galactosidase-induced hydrolysis of the β1[RIGHTWARDS ARROW]4 glycosidic bond in the lactose moiety (red box in picture) allows the release of a dye entrapped in the pores of the hybrid material to the bulk solution.

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