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Zaozao Qiu and Zuowei Xie Nickel-Catalyzed Three-Component [2+2+2] Cycloaddition Reaction of Arynes, Alkenes, and Alkynes Angewandte Chemie International Edition 48

Version of Record online: 25 JUN 2009 | DOI: 10.1002/anie.200902006

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Three in one: Nickel-catalyzed three-component cycloaddition reactions of readily available arynes, activated alkenes, and alkynes gave a series of substituted 1,2-dihydronaphthalenes in moderate to very good yields with excellent chemo- and regioselectivity (see scheme, TMS=trimethylsilyl, cod=1,5-cyclooctadiene).

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