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Xavier Garrabou, José A. Castillo, Christine Guérard-Hélaine, Teodor Parella, Jesús Joglar, Marielle Lemaire and Pere Clapés Asymmetric Self- and Cross-Aldol Reactions of Glycolaldehyde Catalyzed by D-Fructose-6-phosphate Aldolase Angewandte Chemie International Edition 48

Version of Record online: 24 JUN 2009 | DOI: 10.1002/anie.200902065

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New facets of enzyme activity: D-Fructose-6-phosphate aldolase (FSA) catalyzes the self-aldol reaction of glycolaldehyde (GA) and its cross-aldol addition to other aldehydes. As the affinity of GA for FSA as a donor is higher than that as an acceptor, cross-aldol reactions are possible with good to poor aldehyde acceptors if the concentration of GA in the reaction is kept low.

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