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Lisa Diab, Tomáš Šmejkal, Jens Geier and Bernhard Breit Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation–Hydrogenation Angewandte Chemie International Edition 48

Version of Record online: 22 SEP 2009 | DOI: 10.1002/anie.200903620

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The chemoselective reduction of aldehydes and the tandem hydroformylation–hydrogenation of terminal alkenes are possible with a supramolecular catalyst that operates by a novel mechanism involving substrate activation by hydrogen bonding and subsequent metal–ligand bifunctional hydrogenation (see scheme).

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