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Jinshui Zhang, Xiufang Chen , Kazuhiro Takanabe, Kazuhiko Maeda, Kazunari Domen, Jan Dirk Epping, Xianzhi Fu, Markus Antonietti and Xinchen Wang  Synthesis of a Carbon Nitride Structure for Visible-Light Catalysis by Copolymerization Angewandte Chemie International Edition 49

Article first published online: 30 NOV 2009 | DOI: 10.1002/anie.200903886

Thumbnail image of graphical abstract

Just like a melon: Carbon nitride photocatalysts (see formula) structurally akin to poly(aminoimino)heptazine (Liebig′s melon) can be prepared by direct copolymerization of dicyandiamide with barbituric acid (BA). The picture shows how increasing the amount of BA in the copolymerization mixture (arrows) extends the optical absorption of the products further into the visible region, as is favorable for solar-energy applications.

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