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Kateryna Fesko, Michael Uhl, Johannes Steinreiber, Karl Gruber and Herfried Griengl Biocatalytic Access to α,α-Dialkyl-α-amino Acids by a Mechanism-Based Approach Angewandte Chemie International Edition 49

Article first published online: 26 NOV 2009 | DOI: 10.1002/anie.200904395

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New donors—new products: Threonine aldolases (L-TA, D-TA) have now been found to accept donors other than glycine. In a simple asymmetric biocatalytic aldol reaction alanine, serine, and cysteine reacted with a range of simple acceptor aldehydes to yielded α-substituted serine derivatives (see scheme; PLP=pyridoxal phosphate).

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