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Amir H. Hoveyda, Steven J. Malcolmson, Simon J. Meek and Adil R. Zhugralin Catalytic Enantioselective Olefin Metathesis in Natural Product Synthesis. Chiral Metal-Based Complexes that Deliver High Enantioselectivity and More Angewandte Chemie International Edition 49

Article first published online: 3 DEC 2009 | DOI: 10.1002/anie.200904491

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More than meets the eye: The use of chiral olefin metathesis catalysts should not be viewed as relevant only to cases that require control of absolute stereochemistry: such chiral catalysts often offer levels of efficiency, product selectivity, and E/Z stereoselectivity that are unattainable with the achiral variants (see example; TBS=tert-butyldimethylsilyl).

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