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Jin-Gang Liu, Takehiro Ohta, Satoru Yamaguchi, Takashi Ogura, Satoshi Sakamoto, Yonezo Maeda and Yoshinori Naruta Spectroscopic Characterization of a Hydroperoxo–Heme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex Angewandte Chemie International Edition 48

Version of Record online: 30 OCT 2009 | DOI: 10.1002/anie.200904572

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Modeling job: Protonation of a closed seven-coordinate side-on heme peroxide can switch its spin state from high- to low-spin and convert the η2 binding fashion into a monodentate configuration to afford the corresponding hydroperoxide (see scheme). The end-on low-spin ferric hydroperoxo–heme species bear a covalently appended axial imidazole ligand and are easily prepared.

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