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Teng Ben, Hao Ren, Shengqian Ma, Dapeng Cao, Jianhui Lan, Xiaofei Jing, Wenchuan Wang, Jun Xu, Feng Deng, Jason M. Simmons, Shilun Qiu and Guangshan Zhu Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area Angewandte Chemie International Edition 48

Version of Record online: 17 NOV 2009 | DOI: 10.1002/anie.200904637

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Diamonds are forever: A diamond-like framework in which the C–C bonds are replaced with rigid phenyl rings (see picture) is not only structurally stable but also has a large internal surface area. This porous aromatic framework (PAF-1) demonstrates high uptake capacities of hydrogen and carbon dioxide as well as benzene and toluene vapors, and has an unprecedented surface area of 7100 m2 g−1.

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