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Ahsanullah and Jörg Rademann Cyclative Cleavage through Dipolar Cycloaddition: Polymer-Bound Azidopeptidylphosphoranes Deliver Locked cis-Triazolylcyclopeptides as Privileged Protein Binders Angewandte Chemie International Edition 49

Article first published online: 25 JUN 2010 | DOI: 10.1002/anie.200904980

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Support and guidance: Azidopeptidyl phosphoranes on a solid support react very efficiently through cyclative cleavage to yield cyclopeptides with an incorporated triazole ring. The solid support is advantageous as cyclization is favored strongly over oligomerization reactions and thus only cyclized products are released.

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